Jennifer Stockdill

Faculty Profile

Associate Professor
fc0425@wayne.edu

Department

 Chemistry

Phone

313-577-2605

Fax

313-577-8822

Office

Chem 277

Selected publications

Zhu, S.; Samala, G.; Sletten, E. T.; Stockdill, J. L.,* Nguyen, H. M.* Facile Triflic Acid-Catalyzed -1,2-cis-Thiol Glycosylations: Scope and Application to the Synthesis of S-Linked Oligosaccharides, Glycolipids, Sublancin Glycopeptide and TN/TF Antigens. Chem. Sci. 2019, 10, 10475-10480. 

Arbour, C. A.; Belavek, K. J.; Tariq, R.; Mukherjee, S.; Tom, J. K.; Isidro-Llobet, A.; Kopach, M. E.; Stockdill, J. L.* Bringing Macrolactamization Full Circle: Self-Cleaving Head-to-Tail Macrocyclization of Unprotected Peptides via Mild N-Acyl Urea Activation. J. Org. Chem. 2019, 84, 1035–1041. 

Kondasinghe, T. D.; Saraha, H. Y.; Jackowski, S. T.; Stockdill, J. L.* Raising the Bar On-Bead: Efficient On-Resin Synthesis of alpha-Conotoxin LvIA. Tetrahedron Lett. 2019, 60, 23–28.

Sirinimal, H. S.;‡ Hebert, S. P.;‡ Samala, G.; Chen, H.; Rosenhauer, G. J.; Schlegel, H. B.;* Stockdill, J. L.* A Synthetic and Computational Study of Tin-Free Reductive Tandem Cyclizations of Neutral Aminyl Radicals. Org. Lett. 2018, 20, 6340–6344.

Arbour, C. A.; Stockdill, J. L.* A mild capping method for SPPS on the N-methyl diaminobenzoyl linker: synthesis of an N-acyl urea appended C. elegans neuropeptide. Tetrahedron Lett. 2018, 59, 3903–3906.

Lopez, A. M.;‡ Ibrahim, A. I.;‡ Rosenhauer, G. J.; Sirinimal, H. S.; Stockdill, J. L.* Tin-Free Access to the ABC Core of the Calyciphylline A Alkaloids and Unexpected Formation of a D-Ring-Contracted Tetracyclic Core. Org. Lett. 2018, 20, 2216–2219.

Arbour, C. A.;‡ Stamatin, R. E.;‡ Stockdill, J. L.* Divergent C-Terminal Elongation of Peptides. J. Org. Chem. 2018, 83, 1797–1803.

Arbour, C. A.; Kondasinghe, T. D.; Saraha, H. Y.; Vorlicek, T. L.; Stockdill, J. L.* Epimerization-Free Access to C-Terminal Cysteine Peptide Acids, Carboxamides, Amides, and Esters. Chem. Sci. 2018, 9, 350–355.

Arbour, C. A.; Saraha, H. Y.; McMillan, T. F.; Stockdill, J. L.* Exploiting the MeDbz Linker to Generate Protected or Unprotected C-Terminally Modified Peptides. Chem. Eur. J. 2017, 23, 12484–12488.

Kondasinghe, T. D.;‡ Saraha, H. Y.; ‡ Odeesho, S. B.; Stockdill, J. L.* Direct Palladium-Mediated On-Resin Disulfide Formation from Allocam Protected Peptides. Org. Biomol. Chem. 2017, 15, 2914–2918.

Yang, Y.Y.; Ibrahim, A. A.; Hashemi, P.;* Stockdill, J. L.* Real-Time, Selective Detection of Copper(II) using Ionophore-Grafted Carbon-Fiber Microelectrodes. Anal. Chem. 2016, 88, 6962–6966.

Yang, Y.Y; Ibrahim, A. A.; Stockdill, J. L.;* Hashemi, P.* A Density-Controlled Scaffolding Strategy for Covalent Functionalization of Carbon-Fiber Microelectrodes. Anal. Methods 2015, 7, 7352–7357.

Stockdill, J. L.;* Lopez, A. M.; Ibrahim, A. A. Toward the ABCD Core of the Calyciphylline A-Type Daphniphyllum Alkaloids: Solvent non-Innocence in Neutral Aminyl Radical Cyclizations. Tetrahedron Lett. 2015, 56, 3503–3506. Invited Submission to Symposium in Print in Memory of Prof. Harry Wasserman.

Ibrahim, A. A.; Golonka, A. N.; Lopez, A. M.; Stockdill, J. L.* Rapid Access to the Heterocyclic Core of the Calyciphylline A and Daphnicyclidin A-type Daphniphyllum Alkaloids via Tandem Cyclization of a Neutral Aminyl Radical. Org. Lett. 2014, 16, 1072–1075.

Research Description

Research in the Stockdill group will be focused on the design of elegant and efficient strategies for the synthesis of complex natural products and for the synthesis and manipulation of proteins and related structures. Through these efforts, we will explore chemical reactivity and develop new reaction methods.

Please see my website.

http://stockdillgroup.info/app/research-interests/

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